|
Search / Korean Journal of Chemical Engineering
|
HWAHAK KONGHAK, Vol.29, No.3, 284-299, 1991
MRSM-1 모델을 이용한 Group-Group과 상호작용 파라미터 추산에 의한 3성분계 표현
The Representation of Ternary Systems by the Estimation of Group-Group and Interaction Parameters for MRSM-1 Model
새로운 추산방법의 하나로서, 2성분계 및 3성분계의 기상과 액상의 평형온도와 조성사이의 관계를 표현하는 MRSM-1 모델을 제시하였다. MRSM-1 모델을 이용하여 computer graphic에 의해 3성분계의 기액평형 등온선을 도시하였고, 도시된 등온선으로부터 공비점의 존재여부, 형태, 온도 그리고 조성의 주산이 가능해진다.
As one of the new estimation method, the MRSM-1 model which represents the relationship between equilibrium temperatures and compositions of vaper and liquid phase of the binary and ternary systems is proposed. By means of the MRSM-1 model, the temperatures of various compositions of five ternary systems are predicted. Representations of the isothermal lines and estimation of azeotropes are at-tempted using computer graphics. The MRSM-1 model provides a new method of predicting and depicting the isothermal lines, and existence and characteristics of the azeotropes of ternary systems.
[References]
- Beck JV, Arnold KJ, "Parameter Estimation in Engineering and Science," John Wiley and Sons, Inc., N.Y., 1977
- Box GEP, Biometrics, 10, 16, 1954
- Chao KC, Hougen OA, Chem. Eng. Sci., 7, 246, 1958
- Chueh PL, Prausnitz JM, AIChE J., 13(6), 1107, 1967
- Fredenslund A, Gmehling J, Rasmussen P, "Vapor-Liquid Equilibrium Using UNIFAC," Elsevier, 1979
- Gmehling J, Onken U, Arlt W, "Vapor-Liquid Equilibrium Data Collection," DECHEMA, 1981
- Ha DM, Park JC, Theses Collection, Kyung Hee Univ., 14, 451, 1985
- Hill WJ, Hunter WG, Technometrics, 8, 571, 1966
- Hilm AK, Ellis SRM, Barkers PE, Br. Chem. Eng., 15(10), 1321, 1970
- Horsley LE, "Azeotropic Data III," Am. Chem. Soc., 1973
- Kim MG, Park JC, Theses Collection, Kyung Hee Univ., 14, 483, 1985
- King MB, "Phase Equilibrium in Mixture," Pergamon Press, N.Y., 1969
- Lee LL, Startling KE, Fluid Phase Equilib., 21, 77, 1985
- Lee LL, Chung FTH, Landis LH, Fluid Phase Equilib., 31, 253, 1986
- Lu BCY, Li JCH, Ting TW, Ind. Eng. Chem., 51, 219, 1959
- Malesinski W, "Azeotropy and Other Theoretical Problems of Vapor-Liquid Equilibrium," Polish Scientific Publishers, Warszawa, 1965
- Morawetz H, "Macromolecular in Solution," John Wiley and Sons, Inc., N.Y., 1975
- Nagata I, J. Chem. Eng. Data, 7, 461, 1962
- Nakanishi K, Okazak S, Ikali K, Higuchi T, Tanaka H, J. Chem. Phys., 76, 629, 1982
- Park JC, "Prediction of Activity Coefficient for Non-Ideal Liquid Mixture," The 183rd Meeting of European Federation of Chem Engineers at Helsinki Finland, June, 1977
- Park JC, Theses Collection, Kyung Hee Univ., 1, 509, 1980
- Park JC, Theses Collection, Kyung Hee Univ., 11, 139, 1982
- Park JC, PACHEC Proceeding, 2, 340, 1983
- Park JC, "Computer Estimation of Phase Response Surface," 1st ed., Kyung Hee Univ., Publication, 1983
- Park JC, "Estimation of Multicomponent Phase Surface by Means of Response Surface Methodology and Comparison of Fitting for 3 and 4 Component Systems," Kyung Hee Univ., Publication, Seoul, 1985
- Park JC, Theses Collection, Kyung Hee Univ., 15, 239, 1986
- Park JC, "Representation of Multiple Phase Response Surface by Means of Computer Graphics," Kyung Hee Univ., Publication, Seoul, 1987
- Park JC, Ha DM, Theses Collection, Kyung Hee Univ., 16, 495, 1987
- Park JC, Kim MG, HWAHAK KONGHAK, 26(2), 194, 1988
- Park JC, "Mandang, Park, John-Chul, Ph.D., Full Professor, 60th Birthday Anniversary Theses Collection," Munyangsa, Seoul, 1988
- Prausnitz JM, Lichtenthaler RN, deAzevedo EG, "Molecular Thermodynamics of Fluid-Phase Equilibria," Prentice-Hall Englewood Cliff, N.Y., 1986
- Redlich O, Kister AJ, Ind. Eng. Chem., 40, 345, 1948
- Reid RC, Prausnitz JM, Poling BE, "The Properties of Gases and Liquids," 4th Ed., McGraw-Hill, 1987
- Shin HS, Park JC, Theses Collection, Kyung Hee Univ., 17, 497, 1988
- Wilson GM, J. Am. Chem. Soc., 86, 127, 1964
- Wohl K, Trans. AIChE., 42, 215, 1946
[Cited By]
- Ha DM, Mok YS, Choi JW, HWAHAK KONGHAK, 37(2), 146, 1999
- Park JC, Ha DM, Kim MG, Korean Journal of Chemical Engineering, 13(2), 115, 1996
- Kim MG, Ha DM, Park JC, Korean Journal of Chemical Engineering, 12(1), 39, 1995
- Ha DM, Lee S, Choi YC, Oh H, HWAHAK KONGHAK, 41(2), 186, 2003
|