Search / Korean Journal of Chemical Engineering
HWAHAK KONGHAK,
Vol.28, No.4, 403-410, 1990
황산화 폴리아크릴형 내구성 대전방지제에 관한 연구
Studies on the Durable Antistatic Agent of Sulfated Polyacrylate and Additives
4급화 2-dimethyl aminoethyl methacrylate(DMAC)와 N-methylol acrylamide(MAA)를 공중합시켜 모체수지 poly(DMAC-MAA)를 합성하고, 합성된 용성 공중합체에 높은 흡습성을 가진 lithium chlo-ride와 sodium gluconate를 블렌딩시켜 PET 섬유용 대전방지제를 제조하였다. 제조된 대전방지제를 PET직물에 단독 혹은 수지병용으로 처리한 후 내세탁성 실험결과 낮은 표면저항, 적은 값의 미찰대전압 및 짧은 감쇄 반감기 값을 가지는 양호한 대전방지제임이 입증되었다.
Base resin of poly(DMA-MAA) copolymer was synthesized by copolymerizing N-methylol acryl-amide(MAA) with quaternized 2-dimethyl aminoethyl methacrylate(DMAC). Antistatic agent treating to PET woven fabrics was prepared by blending water soluble poly(DMA- MAA)with lithium chloride and sodium gluconate having high hydroscopic properties. Treating with and without resin to PET textile and washing tests revealed that the syn-thesized antistatic agents were good durable ones having low surface resistance, small frictional voltage and short decay half time of electric charge.
[References]
  1. Helmholtz H, J. Am. Phys., 7, 337, 1879
  2. Coehn A, J. Wred. Ann., 64, 217, 1898
  3. Hersh SP, Montgomery DJ, Text. Res. J., 25, 61, 1955
  4. Gonsalves VE, van Dongeren BJ, Text. Res. J., 24, 1, 1954
  5. Hersh SP, Sharman EP, Text. Res. J., 24, 426, 1954
  6. Cunnigham RG, Montgomery DJ, Text. Res. J., 18, 971, 1958
  7. Sugiyama SZ, Surface, 21, 36, 1983
  8. Henshall AE, J. Soc. Dyers Color, 76, 525, 1960
  9. Marumo H, Takai M, Saito M, Kogyo Kag Zasshi, 72, 940, 1969
  10. Wilson N, Text. Inst. Ind., 10, 235, 1972
  11. Mizutani T, Mitani K, Ieda M, Jpn. J. Appl. Phys., 22(4), 677, 1983
  12. Lewis DM, Text. Res. J., 54(5), 279, 1984
  13. Vigo TL, Bruno JS, J. Appl. Polym. Sci., 37(2), 371, 1989
  14. Tambor M, Cope JL, Jerome JL, U.S. Patent, 4,737,156, 1988
  15. Maity NC, Kartha KPR, Srivastava HC, Colourage, 31(24), 11, 1984
  16. Wilson N, Text. J. Austr., 51(7), 10, 1976
  17. Kimura Y, Angew. Makromol. Chem., 132, 169, 1985
  18. Ona I, Ozaki M, Japan Kokai 88, 23, 976, 1988
  19. Kyou Wa Gas Co.: Japan Kokai 86, 40, 258, 1986
  20. Ganmo S, Kogyo Kag. Zasshi, 69, 1504, 1966
  21. Rath H, herbolsheimer E, Stapt S, Text. Res. J., 30, 201, 1960
  22. Marsh JT, "An Introduction to Textile Finishing," 1st ed., p. 247, Chapman & Hall Ltd., New York, 1950
  23. Venkatesh GM, Das TK, Pal S, Atira Tech. Dig., 13(2), 4, 1979
  24. Holmes FH, Heap SA, J. Soc. Dyers Color., 83, 12, 1967
  25. Ganmo S, Kogyo Kag. Zasshi, 72, 940, 1969