Fabrication and material properties of the catalytic oxide electrode, which is known to be so effective to destruct refractory organics in aqueous waste, were studied. A method to enhance the fabrication reproducibility of the oxide electrodes was tested for Ru, Ru-Sn, Ru-Sn-Ti oxide on the Ti substrate, and various physical and material characteristics of the oxide electrodes and an adhesive degree of the oxides to the substrate were examined with changes of sintering temperature, composition of metal oxides, and etching condition, using TGA, AES, XPS, EPMA, SEM and a tape test. The degree of non-stochiometry in the oxide, being attributed to the catalytic property of the oxide electrode, was evaluated. The etching condition of Ti substrate was found to have a severe effect on the fabrication reproducibility, the surface morphology, and the amount of oxide coated on the substrate of the oxide electrode. The metal oxide sintered below 600℃ was confirmed to have a non-stochiometric compound of MO_2-x(0

Keywords: Catalytic Oxide Electrode; DSA; Organic Oxidation; Organic Combustion; Ru Oxide; Etching; Mixed Oxide Electrode

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[Cited By]

1. Kim KW, Lee EH, Kim JS, Shin KH, Kim KH, HWAHAK KONGHAK, 39(2), 138, 2001
2. Kim KW, Lee EH, Kim JS, Shin KH, Jung BI, Kim KH, HWAHAK KONGHAK, 40(2), 146, 2002
3. Kim KW, Lee EH, Kim JS, Shin KH, Jung BI, Journal of the Korean Industrial and Engineering Chemistry, 13(3), 285, 2002

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