Search / Korean Journal of Chemical Engineering
HWAHAK KONGHAK,
Vol.12, No.3, 203-210, 1974
에탄올-물 혼합용매에서 염화카륨의 전도도에 관한 연구
Studies on Electrical Conductivities of Potassium Chloride in Ethanol-Water Mixed Solvent
에탄올-물 혼합용매에서 염화카륨의 전도도를 25∼40℃에서 측정하여 Limiting Equivalent Conductance와 Walden Product를 구하였다.
또한 혼합 용매의 밀도, 점도, 유전상수로부터 용매-용매 및 이온-용매 상호작용을 검토하여 물과 에탄올의 회합으로 물의 구조가 0.1 물분율에서 가장 강화됨을 알았다.
The equivalent conductivity of the potassium chloride was measured at various temperatures between 25 and 40℃ in ethanol-water mixed solvent system. Density, viscosity, and dielectric constant data are also reported for the mixed solvent.
Limiting equivalent conductivity and Walden product as a function of solvent composition and temperature are reported. The interactions between solvent-solvent and ion-solvent are discussed.
Maxima of 0η0 are found for the potassium chloride solutions in 0.1 mole fraction of ethanol. It is assumed that the maxima of 0η0 correspond to an association of water and ethanol with higher degree of hydration than the association of viscosity.