Search / Korean Journal of Chemical Engineering
HWAHAK KONGHAK,
Vol.4, No.3, 193-197, 1966
회분이 많은 무연탄의 와사화반응속도 측정
On the Gassification Rate of Anthracite Coal Abundant in Ash
With CO2 gas and steam, gassification rate of anthracite coal containing various of ashes were measured.
The reaction of C + CO2 and C + H2O in this work is followed the rate of chemical reaction, and was expressed as two stage reaction like M. A. Mayer's work.
C + CO2 Reaction
kc2 = ((2.24×1010)/ T-1/2)․e-(55.790/RT) (900∼1,070 ℃)
kc2 = ((5.89×106/ T-1/2)․e-(33.520/RT) (1,070∼1,250 ℃)
C + H2O Reaction
kc3=((8.77×108)/T-1/2)․e-(43.160/RT) (800∼1,000 ℃)
kc3 = ((2.249×106/ T-1/2)․e-(28.590/RT) (1,000∼1,150 ℃)