About The Journal
  Aims and Scope
  Editorial Board
  Submit a Manuscript 
  Subscription Information
Articles & Issues
  Issue
  Search
For Authors
  Instructions to Authors
  Ethics in Publishing
  Peer Review Process
  Author's Checklist
  Copyright Transfer Form
Contact us
 
 
 
 
Search / Korean Journal of Chemical Engineering
Korean Chemical Engineering Research,
Vol.58, No.1, 1-20, 2020
페로브스카이트 태양전지 안정성 개선을 위한 광활성층 연구 현황과 전망
Future Prospect of Perovskite Solar Cells for Practical Applications
송재관, 김도형
화석 연료를 이용하는 에너지원이 심각한 환경오염을 일으키고, 인류의 건강한 삶에 큰 영향을 주어 청정한 에너지자원의 개발은 매우 중요한 이슈가 되었다. 화석 연료를 대체하기 위한 다양한 에너지원의 개발이 진행되고 있으며, 그 중 최근에는 태양 전지에 대한 관심이 점차 커지고 있다. 현재 실용화 되어 있는 태양전지는 실리콘 기반 태양전지인데, 제조비용이 큰 단점이 부각되고 있으며 이에 따라 이의 단점을 개선하기 위한 노력과 동시에 실리콘 기반 태양전지를 대체하려는 시도가 이루어지고 있다. 이중 실리콘 기반 태양전지를 대체할 후보로 페로브스카이트 태양전지가 큰관심을 받고 있는데, 그 이유는 높은 광전 변환 효율, 저렴한 제조비용, 유연한 형태로의 제조 가능성 때문이다. 그러나 현재 보고되고 있는 페로브스카이트 태양전지는 장기적 안정성이 떨어지며, 또 납으로 인해 신체에 유해하다는 큰단점을 가지고 있다. 본 리뷰에서는 페로브스카이트 태양전지의 장기적 안정성을 높이는 방안들 그리고 환경적으로 유해한 납을 사용하지 않는 방안들의 최신 연구 방향 동향에 관하여 살펴보았다
Development of efficient methods for clean energy production became a critical issue to improve the quality of human lives. Solar cells is considered as one of the alternative solutions to resolve the issue. Although Si-based solar cells are only popularly utilized for practical applications, high manufacturing cost is considered as a serious drawback for further versatile applications. Thus, different types of are being investigated aiming to replace the Si-based solar cells. Recently, perovskite solar cells (PSC) are considered as a potential replacement for Si-based solar cells due to their low production cost, high power conversion efficiency, light weight and possibility of flexible device fabrication. Thus, we have reviewed the challenges of PSC faced with practical application, particularly on stability.
Keywords: Renewable energy; Perovskite solar cell
[References]
  1. Jo W, Choi H, Kim S, Yoo J, Chun D, Rhim Y, Lim J, Lee S, Korean J. Chem. Eng., 32(2), 255, 2015
  2. Kim BS, Kim TY, Park TC, Yeo YK, Korean J. Chem. Eng., 35(9), 1779, 2018
  3. Lu Q, Ali Z, Tang H, Iqbal T, Arain Z, Cui MS, Liu DJ, Li WY, Yang YP, Korean J. Chem. Eng., 36(3), 377, 2019
  4. Kim MY, Ye IS, Ryu CK, Korean J. Chem. Eng., 35(5), 1065, 2018
  5. Yang F, Yu Q, Xie H, Zuo Z, Hou L, Qin Q, Korean J. Chem. Eng., 35(8), 1626, 2018
  6. Barati S, Ghazi MM, Khoshandam B, Korean J. Chem. Eng., 36(1), 146, 2019
  7. Joo D, Han K, Jang JH, Park SK, Korean J. Chem. Eng., 36(2), 299, 2019
  8. Park KT, Oh SR, Won WG, Korean J. Chem. Eng., 36(3), 345, 2019
  9. Ko HS, Park HW, Kim GJ, Lee JD, Korean J. Chem. Eng., 36(4), 620, 2019
  10. Chu C, Kwon BW, Lee W, Kwon Y, Korean J. Chem. Eng., 36, 1372, 2019
  11. Wang X, Kim JH, Choi YB, Kim HH, Kim CJ, Korean J. Chem. Eng., 36(7), 1172, 2019
  12. Yoo HM, Lee JS, Yang WS, Choi HS, Jang HN, Seo YC, Korean J. Chem. Eng., 35(3), 654, 2018
  13. Kim H, Nam S, Jeong J, Lee S, Seo J, Han H, Kim Y, Korean J. Chem. Eng., 31(7), 1095, 2014
  14. Berhe TA, Su WN, Chen CH, Pan CJ, Cheng JH, Chen HM, Tsai MC, Chen LY, Dubale AA, Hwang BJ, Energy Environ. Sci., 9, 323, 2016
  15. Yoo IH, Kalanur SS, Eom K, Ahn B, Cho IS, Yu HK, Jeon HT, Seo HT, Korean J. Chem. Eng., 34(12), 3200, 2017
  16. Zafar M, Yun JY, Kim DH, Korean J. Chem. Eng., 34(5), 1504, 2017
  17. Cho HH, Cho CH, Kang H, Yu H, Oh JH, Kim BJ, Korean J. Chem. Eng., 32(2), 261, 2015
  18. Zafar M, Yun JY, Kim DH, Korean J. Chem. Eng., 35(2), 567, 2018
  19. Lee SY, Seo JY, Kim HJ, Song DI, Kim YK, Korean J. Chem. Eng., 35(12), 2496, 2018
  20. Meng LX, Zhang YM, Wan XJ, Li CX, Zhang X, Wang YB, Ke X, Xiao Z, Ding LM, Xia RX, Yip HL, Cao Y, Chen YS, Science, 361(6407), 1094, 2018
  21. Zheng J, Lau CFJ, Mehrvarz H, Ma FJ, Jiang Y, Deng X, et al., Energy Environ. Sci., 11, 2432, 2018
  22. Quiroz COR, Shen Y, Salvador M, Forberich K, Schrenker N, et al., J. Mater. Chem. A, 6, 3583, 2018
  23. Kim JY, Lee K, Coates NE, Moses D, Nguyen TQ, Dante M, Heeger AJ, Science, 317, 222, 2007
  24. You J, Dou L, Yoshimura K, Kato T, Ohya K, Moriarty T, Emery K, Chen CC, Gao J, Li G, Yang Y, Nature Communications, 4, 1446, 2013
  25. Zhao D, Wang C, Song Z, Yu Y, Chen C, Zhao X, Zhu K, Yan Y, ACS Energy Lett., 3, 305, 2018
  26. Jang KI, Hong E, Kim JH, Korean J. Chem. Eng., 30(3), 620, 2013
  27. Yang J, Lin Y, Meng Y, Korean J. Chem. Eng., 30(11), 2026, 2013
  28. Park S, Son MK, Kim SK, Jeong MS, Prabakar K, Kim HJ, Korean J. Chem. Eng., 30(11), 2088, 2013
  29. Umale S, Sudhakar V, Sontakke SM, Krishnamoorthy K, Pandit AB, Mater. Res. Bull., 109, 222, 2019
  30. Klunder KJ, Elliott CM, Henry CS, J. Mater. Chem. A, 6, 2767, 2018
  31. So S, Hwang I, Yoo J, Mohajernia S, Mackovic M, Spiecker E, Cha G, Mazare A, Schmuki P, Adv. Eng. Mater., 8, 180098, 2018
  32. J. Mol. Cell. Cardiol., Santos GCD, Oliveira EF, Lavarda FC, Silva-Filho LCD, Journal of Molecular Modeling, 25, 75(2019).
  33. Aksoy S, Gorgun K, Caglar Y, Caglar M, J. Mol. Struct., 1189, 181, 2019
  34. Chu VB, Park SJ, Park GS, Jeon HS, Hwang YJ, Min BK, Korean J. Chem. Eng., 33(3), 880, 2016
  35. Kim JH, Shin HB, Korean J. Chem. Eng., 36(2), 305, 2019
  36. Lee D, Yong K, Korean J. Chem. Eng., 30(7), 1347, 2013
  37. Truong NTN, Trinh KT, Pham VTH, Kim CD, Park C, Korean J. Chem. Eng., 32(4), 761, 2015
  38. Pejjai B, Reddy VRM, Keku K, Cho HY, Pallavolu MR, Le TTT, Jeong DS, Kotte TRR, Park CH, Korean J. Chem. Eng., 35(12), 2430, 2018
  39. Green, Hishikawa MA, Dunlop Y, Levi ED, Ebinger DH, Yoshita M, Ho-Baillie AWY, Prog Photovolt Res Appl., 27, 3, 2019
  40. Green MA, J. Mater. Sci. Mater. Electron, 18, S15, 2007
  41. Kojima A, Teshima K, Shirai Y, Miyasaka T, J. Am. Chem. Soc., 131(17), 6050, 2009
  42. Kim HS, Lee CR, Im JH, Lee KB, Moehl T, Marchioro A, Scientific Reports, 2, 591, 2012
  43. Yin WJ, Yang JH, Kang J, Yan Y, Wei SH, J. Mater. Chem. A, 3, 8926, 2015
  44. Elumalai N, Mahmud M, Wang D, Uddin A, Energies, 9, 861, 2016
  45. Song Z, Watthage SC, Phillips AB, Heben MJ, J. of Photonics for Energy, 6, 022001 (2016).
  46. Green MA, Ho-Baillie A, Snaith HJ, Nature Photonics, 8, 506, 2014
  47. Xu Z, Teo SH, Gao L, Guo Z, Kamata Y, Hayase S, Ma T, Organic Electronics, (2019).
  48. Shin SS, Suk JH, Kang BJ, Yin W, Lee SJ, Noh JH, Ahn TK, Rotermund F, Cho IS, Seok SL, Energy Environ. Sci., 12, 958, 2019
  49. Xia F, Wu Q, Zhou P, Li Y, Chen X, Liu Q, Zhu J, Dai S, Lu Y, Yang S, ACS Appl. Mater. Interfaces, 7, 13659, 2015
  50. Tan H, Jain A, Voznyy O, Lan X, Arquer FPGD, Fan JZ, et al., Science, 355, 722, 2017
  51. Kermanpur EHAA, Steier L, Domanski K, Matsui T, Tress W, Saliba M, Abate A, Gratzel M, Hagfeldt A, Correa-Baena JP, Energy Environ. Sci., 9, 3128, 2016
  52. Seo JY, Uchida R, Kim HS, Saygili Y, Luo J, Moore C, Kerrod J, Wagstaff A, Eklund M, McIntyre R, Pellet N, Zakeeruddin SM, Hagfeldt A, Gratzel M, Adv. Funct. Mater., 28, 170576, 2018
  53. Yang D, Yang R, Wang K, Wu C, Zhu X, Feng J, Ren X, Fang G, Priya S, Liu SF, Nature Communications, 9, 3239, 2018
  54. Gong X, Sun Q, Liu S, Liao P, Shen Y, Gratzel C, Zakeeruddin SM, Gratzel M, Wang M, Nano Lett., 18, 3969, 2018
  55. Singh R, Giri A, Pal M, Thiyagarajan K, Kwak J, Lee JJ, Jeong U, Cho K, J. Mater. Chem. A, 7, 7151, 2019
  56. Pulvirenti F, Wegner B, Noel NK, Mazzotta G, Hill R, et al., Mol. Syst. Des. Eng., 3, 741, 2018
  57. Anaraki EH, Kermanpur A, Mayer MT, Steier L, Ahmed T et al., ACS Energy Lett., 3, 773, 2018
  58. Jeon NH, Na H, Jung EH, Yang TY, Lee YG, Kim G, Shin HW, Seok SI, Lee J, Seo J, Nature Energy, 3, 682, 2018
  59. Kim YC, Yang TY, Jeon NJ, Im J, Jang S, Shin TJ, Shin HW, Kim S, Lee E, Kim S, Noh JH, Seok SI, Seo J, Energy Environ. Sci., 10, 2109, 2017
  60. Zhang L, Zhou X, Zhong X, Cheng C, Tian Y, Xu B, Nano Energy, 57, 248, 2019
  61. Wang KC, Jeng JY, Shen PS, Chang YC, Diau EW, Scientific Reports, 4, 4756, 2014
  62. Rakstys K, Paek S, Gao P, Gratia P, Marszalek T, Grancini G, Cho KT, Genevicius K, Jankauskas V, Pisula W, Nazeeruddin MK, J. Mater. Chem. A, 5, 7811, 2017
  63. Christians JA, Schulz P, Tinkham JS, Schloemer TH, Harvey SP, Villers BJTD, Sellinger A, Berry JJ, Luther JM, Nature Energy, 3, 68, 2018
  64. Nie W, Tsai H, Blancon JC, Liu F, Stoumpos CC, Traore B et al., Adv. Mater., 30, 170387, 2018
  65. Mali SS, Hong CK, Nanoscale, 8, 10528, 2016
  66. Tavakoli MM, Tress W, Milic JV, Kubicki D, Emsley L, Gratzel M, Energy Environ. Sci., 11, 3310, 2018
  67. Chen W, Zhou Y, Wang LG, Wu Y, Tu B, Yu B, Liu F, Tam HW, Wang G, Djurisic AB, Huang L, He Z, Adv. Mater., 30, 180051, 2018
  68. Yu JC, Hong JA, Jung ED, Kim DB, Baek SM, Lee S, Cho S, Park SS, Choi KJ, Song MH, Scientific Reports, 8, 1070, 2018
  69. Calio L, Salado M, Kazim S, Ahmad S, Joule, 2, 1800, 2018
  70. Bruijnaers BJ, Schiepers E, Weijtens CHL, Meskers SCJ, Wienk MM, Janssen RAJ, J. Mater. Chem. A, 6, 6882, 2018
  71. Wu WQ, Wang Q, Fang Y, Shao Y, Tang S, Deng Y, Lu H, Liu Y, Li T, Yang Z, Gruverman A, Huang J, Nature Communications, 9, 1625, 2018
  72. Mali SS, Kim H, Kim HH, Shim SE, Hong CK, Materials Today, 21, 483, 2018
  73. Zhang J, Xu B, Yang L, Ruan C, Wang L, Liu P, Zhang W, et al., Adv. Eng. Mater., 8, 170120, 2018
  74. Domanski K, Correa-Baena JP, Mine N, Nazeeruddin MK, Abate A, Saliba M, Tress W, Hagfeldt A, Gratzel M, ACS Nano, 10, 6306, 2016
  75. Baranwal AK, Kanaya S, Peiris TAN, Mizuta G, Nishina T, Kanda H, Miyasaka T, Segawa H, Ito S, ChemSusChem, 9, 2604, 2016
  76. Yang M, Li J, Li JH, Yuan ZT, Zou JJ, Lei G, Zhao L, Wang XB, Dong BH, Wang SM, J. Power Sources, 424, 61, 2019
  77. Aitola K, Domanski K, Correa-Baena JP, Sveinbjornsson K, et al., Adv. Mater., 29, 160639, 2017
  78. Luo DY, Yang WQ, Wang ZP, Sadhanala A, Hu Q, Su R, Shivanna R, Trindade GF, Watts JF, Xu ZJ, Liu TH, Chen K, Ye FJ, Wu P, Zhao LC, Wu J, Tu YG, Zhang YF, Yang XY, Zhang W, Friend RH, Gong QH, Snaith HJ, Zhu R, Science, 360(6396), 1442, 2018
  79. Nouri E, Mohammadi MR, Lianos P, Carbon, 126, 208, 2018
  80. Cai Y, Zhang Z, Zhou Y, Liu H, Qin Q, Lu X, Gao X, Shui L, Wu S, Liu J, Electrochimica Acta, 261, 445, 2018
  81. Kim YY, Park EY, Yang TY, Noh JH, Shin TJ, Jeona NJ, Seo J, J. Mater. Chem. A, 6, 12447, 2018
  82. Zhang P, Wu J, Zhang T, Wang Y, Liu D, Chen H, Ji L, Liu C, Ahmad W, Chen ZD, Li S, Adv. Mater., 30, 170373, 2018
  83. Song Z, Abate A, Watthage SC, Liyanage GK, Phillips AB, Steiner U, Graetzel M, Heben MJ, Adv. Eng. Mater., 6, 160084, 2016
  84. Rong YG, Hu Y, Mei AY, Tan HR, Saidaminov MI, Seok SI, McGehee MD, Sargent EH, Han HW, Science, 361(6408), 1214, 2018
  85. Son DY, Kim SG, Seo JY, Lee SH, Shin H, Lee D, Park NG, J. Am. Chem. Soc., 140(4), 1358, 2018
  86. Jung HS, Park NG, Small, 11, 10, 2015
  87. Turren-Cruz SH, Saliba M, Mayer MT, Juarez-Santiesteban H, Mathew X, Nienhanus L, et al., Energy Environ. Sci., 11, 78, 2018
  88. Singh T, Miyasaka T, Adv. Eng. Mater., 8, 170067, 2018
  89. Turren-Cruz SH, Hagfeldt A, Saliba M, Science, 362(6413), 449, 2018
  90. Gong J, Yang M, Rebollar D, Rucinski J, Liveris Z, Zhu K, Xu T, Adv. Mater., 1800973(2018).
  91. Zhao W, Yao Z, Yu F, Yang D, Liu SF, Adv. Sci., 5, 170013, 2018
  92. Jiang J, Wang Q, Jin Z, Zhang X, Lei J, Bin H, Zhang ZG, Li Y, Liu SF, Adv. Eng. Mater., 8, 170175, 2018
  93. Tavakoli MM, Bi D, Pan L, Hagfeldt A, Zakeeruddin SM, Gratzel M, Adv. Eng. Mater., 8, 180027, 2018
  94. Yu JC, Badgujar S, Jung ED, Singh VK, Kim DW, Gierschner J, Lee EG, Kim YS, Cho S, Kwon MS, Song MH, Adv. Mater., 31, 180555, 2019
  95. Soe CMM, Nie W, Stoumpos CC, Tsai H, Blancon JC, Liu F, Even J, Marks TJ, Mohite AD, Kanatzidis MG, Adv. Eng. Mater., 8, 170097, 2018
  96. Kim M, Motti SG, Sorrentino R, Petrozza A, Energy Environ. Sci., 11, 2609, 2018
  97. Hwang I, Jeong I, Lee J, Ko MJ, Yong K, ACS Appl. Mater. Interfaces, 7, 17330, 2015
  98. Lin J, Lai M, Dou L, Kley CS, Chen H, Peng F, Sun J, et al., Nature Materials, 17, 261, 2018
  99. Tsai H, Asadpour R, Blancon JC, Stoumpos CC, Durand O, Strzalka JW, Chen B, Verduzco R, Ajayan PM, Tretiak S, Even J, Alam MA, Kanatzidis MG, Nie W, Mohite AD, Science, 360(6384), 67, 2018
  100. Bu X, Westbrook RJE, Lanzetta L, Ding D, Chotchuangchutchaval T, Aristidou N, Haque SA, Sol. RRL, 3, 180028, 2019
  101. Matsui T, Yokoyama T, Negami T, Sekiguchi T, Saliba M, Gratzel M, Segawa H, Chem. Lett., 47(6), 814, 2018
  102. Ke W, Kanatzidis MG, Nature Communications 10, (2019).
  103. Noel NK, Stranks SD, Abate A, Wehrenfennig C, Guarnera S, et al., Energy Environ. Sci., 7, 3061, 2014
  104. Nie R, Mehta A, Park BW, Kwon HW, Im J, Seok SI, J. Am. Chem. Soc., 140(3), 872, 2018
  105. Song TB, Yokoyama T, Stoumpos CC, Logsdon J, Cao DH, Wasielewski MR, Aramaki S, Kanatzidis MG, J. Am. Chem. Soc., 139(2), 836, 2017
  106. Ito N, Kamarudin MA, Hirotani D, Zhang Y, Shen Q, Ogomi Y, Iikubo S, Minemoto T, Yoshino K, Hayase S, J. Phys. Chem. Lett., 9, 1682, 2018
  107. Liao WQ, Zhao DW, Yu Y, Grice CR, Wang CL, Cimaroli AJ, Schulz P, Meng WW, Zhu K, Xiong RG, Yan YF, Adv. Mater., 28(42), 9333, 2016
  108. Chen M, Ju MG, Garces HF, Carl AD, Ono LK, Hawash Z, Zhang Y, Shen T, Qi Y, Grimm RL, Pacifici D, Zeng XC, Zhou Y, Padture NP, Nature Communications 10, (2019).,
  109. Shao S, Liu J, Portale G, Fang HH, Blake GR, Brink GHT, Koster LJA, Loi MA, Adv. Eng. Mater., 8, 170201, 2018
[Cited By]
  1. Lee JH, Lee JH, Korean Journal of Chemical Engineering, 38(9), 1757, 2021
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.