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Search / Korean Journal of Chemical Engineering
Korean Chemical Engineering Research,
Vol.56, No.4, 536-541, 2018
Application of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory to Excess Molar Volumes of Isomers of Propanol with Cyclohexane or n-Hexane
Gahlyan S, Verma S, Rani M, Maken S
Excess molar volumes (Vm E ) of binary mixtures of 1-propanol or 2-propanol (1) + cyclohexane or n-hexane (2) were measured with V-shaped dilatometer at 303.15 K. The Vm E data for these mixtures varied as: 2-propanol > 1-propanol and were higher for cyclohexane than n-hexane for both propanol systems. The experimental data were correlated with Redlich-Kister polynomial. The Vm E data were interpreted qualitatively as well as quantitatively in terms of Flory- Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory. Both models correctly described the sign and shape of Vm E vs x1 curves. The values calculated by both the models agree well with the experimental data.
Keywords: Excess volume; Propanol; Cyclohexane; n-Hexane; Flory-Treszczanowicz-Benson model; Prigogine-Flory-Patterson theory
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[Cited By]
  1. Verma S, Gahlyan S, Rani M, Maken S, Korean Chemical Engineering Research, 56(5), 663, 2018
  2. Gahlyan S, Devi R, Verma S, Rani M, Park SJ, Maken S, Korean Journal of Chemical Engineering, 37(7), 1181, 2020
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