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Search / Korean Journal of Chemical Engineering
Korean Chemical Engineering Research,
Vol.55, No.6, 854-860, 2017
Polysulfone에 Di-(2-ethylhexyl)-phosphoric acid와 Carbon Nanotubes를 고정화한 PSf/D2EHPA/CNTs 비드의 제조와 Sr(II)의 제거 특성
Preparation of PSf/D2EHPA/CNTs Beads Immobilized with Carbon Nanotubes and Di-(2-ethylhexyl)-phosphoric acid on Polysulfone and Removal Characteristics of Sr(II)
이민규, 윤종원, 서정호
본 연구에서는 di-(2-ethylhexyl)-phosphoric acid (D2EHPA)와 carbon nanotubes (CNTs)를 polysulfone (PSf)에 고정화시켜 PSf/D2EHPA/CNTs 비드를 제조하였으며, 제조한 비드에 의한 Sr(II)의 제거특성을 살펴보았다. Scanning electron microscopy (SEM), Fourier transform infrared spectrometer (FTIR) 및 Thermo gravimetric analysis (TGA) 분석을 통하여 PSf/D2EHPA/CNTs 비드의 형태적 특성들을 조사하였다. PSf/D2EHPA/CNTs 비드에 의한 Sr(II)의 제거는 운전시간 60 min 정도에서 평형에 도달하였으며, 속도 실험결과는 유사 2차 속도식에 잘 부합하는 것으로 나타났다. 또한 PSf/D2EHPA/CNTs 비드에 의한 Sr(II)의 제거에서 Langmuir 식으로부터 구한 최대 제거량은 4.75 mg/g이었다. PSf/D2EHPA/CNTs 비드에 의한 Sr(II)의 제거효율은 추출제 D2EHPA 만을 사용하는 경우보다 CNTs를 첨가함으로써 Sr(II)의 제거량이 2.5배 정도 향상되는 결과를 보였다.
PSf/D2EHPA/CNTs beads were prepared by immobilizing extractant di-(2-ethylhexyl)- phosphoric acid (D2EHPA) and adsorbent carbon nanotubes (CNTs) on polysulfone (PSf), and the adsorption characteristics of Sr(II) on the beads were studied. The morphological characteristics of the prepared PSf/D2EHPA/CNTs beads were observed by scanning electron microscopy (SEM), thermo gravimetric analysis (TGA), and Fourier transform infrared spectrometer (FTIR). The equilibrium time for the removal of Sr(II) by PSf/D2EHPA/CNTs beads was 60 min. The experimental kinetic data followed pseudo-second-order model more than pseudo-first-order kinetics model. The maximum removal capacity of Sr(II) obtained from Langmuir isotherm was 4.75 mg/g. The removal efficiencies of Sr (II) by PSf/D2EHPA/ CNTs beads were improved 2.5 times by adding the adsorbent CNTs more than by using only the extractant D2EHPA.
Keywords: Carbon nanotubes; CNTs; Di-(2-ethylhexyl)-phosphoric acid; D2EHPA; Immobilization; Polysulfone; Sr(II) removal
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[Cited By]
  1. Kam SK, Suh JH, Yun JW, Lee MG, Applied Chemistry for Engineering, 29(3), 264, 2018
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