Although biomass syngas is very low calorific gas, it is utilized by means of dual fuel combustion technology in the fields of industrial furnace and boiler as a substitute oil technology. The basic structure of duel fuel combustion burner is designed so that low caloric gas fuel is supplied around an oil burner in the middle. In the present study, three types of mixing burners were manufactured to conduct performance experiment. Low caloric gas was evenly distributed around the oil burner and the method of changing the angle of gas nozzle was applied. CO generation decreased according to the increase of the amount of air for combustion. In addition, the shapes and colors of flame changed according to the proportions of gas and oil used. Remained flame after combustion was from the lack of atomization at the exit of oil burner. Although it was difficult to maintain the optimum air ratio due to different required air ratio for oil and syngas, stable combustion was able to maintained within excess oxygen concentration of 4.7~8.2%. From this study, it was shown that the oil atomization at the exit of fuel oil nozzle was promoted by the increased rate of syngas combustion and the CO concentration in flue gas lower than only fuel oil combustion.